What Does Hexane and Oxygen Make?

When hexane and oxygen react, they form a variety of products, including carbon dioxide, water, and various organic compounds. The specific products formed and the relative proportions of each product depend on the reaction conditions, such as temperature, pressure, and the presence of a catalyst.

Combustion

Under normal conditions, hexane reacts with oxygen in a process called combustion. This is a highly exothermic reaction, meaning that it releases a large amount of heat. The products of combustion are carbon dioxide and water:

“`
2C<sub>6</sub>H<sub>14</sub> + 19O<sub>2</sub> → 12CO<sub>2</sub> + 14H<sub>2</sub>O + heat
“`

Combustion is used to power engines and to generate heat for homes and businesses.

Partial Oxidation

Under certain conditions, hexane can react with oxygen in a process called partial oxidation. This reaction is less exothermic than combustion and produces a variety of organic compounds, including alcohols, aldehydes, and ketones. The specific products formed depend on the reaction conditions.

Partial oxidation is used to produce a variety of chemicals, including acetic acid, which is used to make vinegar and other products.

Autoxidation

Hexane can also react with oxygen in a process called autoxidation. This reaction is initiated by the presence of free radicals and can lead to the formation of peroxides, hydroperoxides, and other oxygenated compounds. Autoxidation can be a problem in the storage and handling of hexane, as it can lead to the formation of gums and other undesirable products.

Autoxidation can be prevented by the addition of antioxidants, which are compounds that scavenge free radicals.

Conclusion

The reaction between hexane and oxygen can produce a variety of products, depending on the reaction conditions. Combustion is a highly exothermic reaction that produces carbon dioxide and water. Partial oxidation produces a variety of organic compounds, including alcohols, aldehydes, and ketones. Autoxidation is a free radical-initiated reaction that can lead to the formation of peroxides, hydroperoxides, and other oxygenated compounds.

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